Impact Factor:

13.3

DOI number:

10.1016/j.cej.2014.02.059

Affiliation of Author(s):

重庆工商大学

Teaching and Research Group:

化学工程系

Journal:

chemical engineering journal

Funded by:

重庆市科技局，催化基础国家重点实验室

Key Words:

CeCu composite oxides；Ordered mesoporous；Phenyl VOCs；Catalytic combustion；Reactive oxygen species

Abstract:

CeCu composite oxide catalysts were prepared by a hard-template method using different mole ratios of Ce/Cu (being designated as CeCu-HTx, where x is the Ce/Cu molar ratio). The prepared catalysts were characterized by XRD, TEM, AAS, XPS, and H2-TPR. The catalytic properties of the prepared CeCu composite oxide catalysts were also investigated by phenyl VOCs (benzene, toluene, xylene, and ethylbenzene) catalytic combustion in air. XRD results showed that the CuO species can fully dissolve into the CeO2 lattice to form CeCu solid solutions having the fluorite structure of crystal-phase CeO2. TEM and low-angle XRD results indicated that CeCu-HT3 had a well-ordered and developed mesoporous structure with uniform pore size, which is better than the CeCu-HT2 and CeCu-HT4. XPS and H2-TPR results showed that CeCu-HT3 had abundant active oxygen species and superior reducibility. CeCu-HT3 had higher toluene catalytic combustion activity than CeCu-HT2 and CeCu-HT4 in air. The minimum reaction temperature at which toluene conversion exceeded 90% on CeCu-HT3 was 225 °C. Toluene catalytic combustion conversion on CeCu-HT3 at 240 °C exceeded 99.3% with decreased toluene concentration in air to below 70 ppm. The phenyl VOCs catalytic combustion activity on the CeCu-HT3 catalyst follows the order ethylbenzene > toluene > xylene > benzene. The CeCu-HT3 catalyst shows high stability and efficiency for toluene catalytic combustion in air. And the CeCu-HT3 catalyst can be applied in purification treatments for air containing a wide range of toluene concentrations.

First Author:

Guilin Zhou

Co-author:

兰海,高涛涛,XHM

Indexed by:

源刊论文

Correspondence Author:

周桂林

Document Code:

O0SDRJVAHG33I1SZX3T1XCSKZ41L2FPL

Discipline:

Engineering

First-Level Discipline:

Chemical Engineering and Technology

Document Type:

Journal Article

Issue:

246

Page Number:

53–63

Translation or Not:

no

Date of Publication:

2014-06-01

Links to published journals:

https://doi.org/10.1016/j.cej.2014.02.059