Role of metal Cu species on methyl laurate catalytic hydrogenation to oxygen-containing compounds
- 影响因子:
- 3.932
- DOI码:
- 10.1016/j.jscs.2020.08.002
- 所属单位:
- 重庆工商大学
- 教研室:
- 化学工程系
- 发表刊物:
- Journal of Saudi Chemical Society
- 项目来源:
- 重庆市科技局
- 关键字:
- Cu/c-Al2O3 catalyst; Catalytic hydrogenation; Methyl laurate; C12 alcohol
- 摘要:
- The Cu/c-Al2O3 catalysts with different Cu loadings were prepared by impregnationmethod. The physicochemical properties of these Cu/c-Al2O3 catalysts were characterized by H2-TPR, XRD, and in-situ XPS. The catalytic hydrogenation performances of methyl laurate overCu/c-Al2O3 catalysts were studied. The results show that the hydrogenation performances of methyllaurate on Cu/c-Al2O3 catalyst are related to the dispersion, crystallite size, and content of theactive component Cu0. The 10CA catalyst has the best hydrogenation performances for methyl laurate to produce C12 alcohol. At 300 C, the conversion of methyl laurate and the selectivity of C12alcohol are 55.6% and 30.4%, respectively.
- 第一作者:
- Fengjiao Wang
- 合写作者:
- Zhifa Cheng,Hongmei Xie,Benjing Xu,Zhaojie Jiao,Xianming Zhang
- 论文类型:
- 源刊论文
- 通讯作者:
- Guilin Zhou
- 学科门类:
- 工学
- 文献类型:
- Journal Article
- 卷号:
- 24
- 期号:
- 10
- 页面范围:
- 733–741
- 是否译文:
- 否
- 发表时间:
- 2020-10-01
- 收录刊物:
- SCI